Blood vessels Blood vessels have a range of different sizes and structures, depending on their role in the body. Arteries Oxygenated blood is pumped from the heart along arteries, which are muscular. Arteries divide like tree branches until they are slender. The largest artery is the aorta, which connects to the heart and picks up oxygenated blood from the left ventricle. The only artery that picks up deoxygenated blood is the pulmonary artery, which runs between the heart and lungs. Capillaries The arteries eventually divide down into the smallest blood vessel, the capillary. Capillaries are so small that blood cells can only move through them one at a time. Oxygen and food nutrients pass from these capillaries to the cells. Capillaries are also connected to veins, so wastes from the cells can be transferred to the blood. Veins Veins have one-way valves instead of muscles, to stop blood from running back the wrong way. Generally, veins carry deoxygenated blood from ...